Surface Free Energy Components by Polar/Dispersion and Acid—Base Analyses; and Hansen Solubility Parameters for Various Polymers

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This table highlights polar/dispersion and acid—base breakouts of surface free energy, as well as Hansen Solubility Parameters and radius of interaction, for a variety of polymers. For all columns except polymer name, CAS #, and total Hansen Solubility Parameter (δ) the first row of data for each material is the average of surveyed values; the second row shows the standard deviation, with the number of data points (n) in parentheses. For n = 1, no standard deviation figure is shown. Click on any column's footnote for details. Click on any polymer name for original research results. An analogous table, which includes contact angle data, can be seen here. Comments on methodology and the like can be found here.

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Surface Free Energy Components by Polar/Dispersion and Acid—Base Analyses; and Hansen Solubility Parameters for Various Polymers

			Polar/Dispersion				Acid-Base						Hansen Parameters
Name⁽¹⁾	CAS #⁽²⁾		γ_S⁽³⁾	γ_S^d⁽⁴⁾	γ_S^P⁽⁵⁾		γ_S⁽⁶⁾	γ_S^LW⁽⁷⁾	γ_S^AB⁽⁸⁾	γ_S⁺ ⁽⁹⁾	γ_S^- ⁽¹⁰⁾		δ⁽¹¹⁾	δ_D⁽¹²⁾	δ_P⁽¹³⁾	δ_H⁽¹⁴⁾	R_o⁽¹⁵⁾

Acrylonitrile butadiene styrene (ABS)	9003-56-9		43.6	35.8	8.0		38.6	39.4	-0.8	0.9	3.7		19.2	17.0	5.7	6.8	9.4
Acrylonitrile butadiene styrene (ABS)			4.83(5)	2.77(5)	2.55(5)		4.81(2)	0.00(2)	4.88(2)	0.14(2)	2.76(2)			0.92(2)	4.17(2)	0.49(2)	2.19(2)
Aluminum foil ^(b)	7429-90-5		41.2	31.7	9.5		-	-	-	-	-		-	-	-	-	-
Aluminum foil ^(b)			2.47(2)	0.57(2)	1.91(2)
Amorphous fluoropolymer (Teflon AF)	-		-	-	-		-	-	-	-	-		-	-	-	-	-
Amorphous fluoropolymer (Teflon AF)
Aramid (Kevlar)	26125-61-1		-	-	-		-	-	-	-	-		-	-	-	-	-
Aramid (Kevlar)
Cellophane	9005-81-6		45.4	29.8	15.6		-	-	-	-	-		28.5	16.1	18.5	14.5	7.3
Cellophane			-(1)	-(1)	-(1)									-(1)	-(1)	-(1)	-(1)
Cellulose acetate butyrate (CAB)	9004-36-8		-	-	-		-	-	-	-	-		22.2	17.2	13.8	2.8	12.6
Cellulose acetate butyrate (CAB)													-(1)	-(1)	-(1)	-(1)
Cellulose acetate (CA)	9004-35-7		42.0	31.0	11.1		43.5	39.0	4.5	0.3	22.2		23.5	17.1	13.1	9.4	10.6
Cellulose acetate (CA)			5.44(2)	1.84(2)	3.61(2)		6.42(4)	4.20(4)	3.25(4)	0.33(4)	2.71(4)			1.58(4)	4.41(4)	3.81(4)	2.96(4)
Cellulose triacetate	9012-09-3		-	-	-		-	-	-	-	-		-	-	-	-	-
Cellulose triacetate
Eicosane	112-95-8		-	-	-		-	-	-	-	-		-	-	-	-	-
Eicosane
Epoxies	-		45.0	37.2	7.8		-	-	-	-	-		24.1	19.2	10.9	9.6	11.1
Epoxies			4.63(5)	4.68(5)	7.00(5)									2.53(13)	2.37(13)	2.66(13)	3.98(13)
Ethyl cellulose	9004-57-3		-	-	-		28.6	27.4	1.2	0.04	8.6		20.4	19.0	5.6	4.9	7.9
Ethyl cellulose							-(1)	-(1)	-(1)	-(1)	-(1)			1.56(2)	1.84(2)	1.41(2)	2.83(2)
Ethyl methacrylate (EMA)	97-63-2		42.0	38.8	3.2		-	-	-	-	-		-	-	-	-	-
Ethyl methacrylate (EMA)			1.06(2)	0.42(2)	0.64(2)
Ethylene-propylene-diene-monomer (EPDM)	25038-36-2		35.5	29.7	5.8		-	-	-	-	-		-	-	-	-	-
Ethylene-propylene-diene-monomer (EPDM)			-(1)	-(1)	-(1)
Fluorinated ethylene polypropylene (FEP)	25067-11-2		19.9	17.1	2.8		17.9	17.9	0.0	0.0	0.0		19.6	19.0	4.0	3.0	4.0
Fluorinated ethylene polypropylene (FEP)			2.90(3)	2.66(3)	2.51(3)		-(1)	-(1)	-(1)	-(1)	-(1)			-(1)	-(1)	-(1)	-(1)
Hexatriacontane	630-06-8		23.7	23.6	0.1		-	-	-	-	-		-	-	-	-	-
Hexatriacontane			6.71(3)	6.78(3)	0.12(3)
2-Hydroxyethyl methacrylate (HEMA, ethylene glycol monoacrylate)	867-77-9		56.8	36.3	20.5		-	-	-	-	-		-	-	-	-	-
			1.20(2)	0.49(2)	0.71(2)
Nafion	31175-20-9		-	-	-		-	-	-	-	-		-	-	-	-	-
Nafion
Nitrocellulose (cellulose nitrate)	9004-70-0		-	-	-		45.1	44.8	0.3	0.01	13.3		23.5	16.2	14.1	9.5	10.7
Nitrocellulose (cellulose nitrate)							0.14(2)	0.21(2)	0.35(2)	0.01(2)	3.75(2)			1.06(2)	0.85(2)	1.06(2)	1.13(2)
Nylon 10,10	-		-	-	-		-	-	-	-	-		-	-	-	-	-
Nylon 10,10
Nylon 11	25587-80-8		-	-	-		-	-	-	-	-		20.5	17.0	4.4	10.6	5.1
Nylon 11														-(1)	-(1)	-(1)	-(1)
Nylon 12	24937-16-4		38.2	33.1	5.2		41.3	37.0	4.3	0.6	7.6		22.2	18.5	8.1	9.1	6.3
Nylon 12			3.46(2)	3.96(2)	0.42(2)		-(1)	-(1)	-(1)	-(1)	-(1)			-(1)	-(1)	-(1)	-(1)
Nylon 2 (polyglycine)	25718-94-9		50.1	27.9	22.2		-	-	-	-	-		-	-	-	-	-
Nylon 2 (polyglycine)			-(1)	-(1)	-(1)
Nylon 4	24938-56-5		48.5	27.8	20.7		-	-	-	-	-		-	-	-	-	-
Nylon 4			-(1)	-(1)	-(1)
Nylon 6,10	9008-66-6		-	-	-		-	-	-	-	-		-	-	-	-	-
Nylon 6,10
Nylon 6,12	24936-74-1		67.0	62.0	4.7		-	-	-	-	-		-	-	-	-	-
Nylon 6,12			-(1)	-(1)	-(1)
Nylon 6,6	32131-17-2		44.8	36.3	9.8		40.2	36.9	3.3	1.5	12.1		25.8	17.2	9.9	16.5	4.4
Nylon 6,6			3.07(8)	5.63(9)	4.03(8)		3.61(2)	0.71(2)	2.90(2)	2.11(2)	13.5(2)			1.11	1.10	6.80	1.24
Nylon 6 (polycaprolactum, aramid 6)	25038-54-4		42.7	33.1	9.6		45.3	42.5	2.8	0.2	9.6		20.3	17.0	3.4	10.6	5.1
Nylon 6 (polycaprolactum, aramid 6)			6.08(2)	2.69(2)	3.39(2)		-(1)	-(1)	-(1)	-(1)	-(1)			-(1)	-(1)	-(1)	-(1)
Nylon 7,7	-		-	-	-		-	-	-	-	-		-	-	-	-	-
Nylon 7,7
Nylon 8,8	-		-	-	-		-	-	-	-	-		-	-	-	-	-
Nylon 8,8
Nylon 9,9	-		-	-	-		-	-	-	-	-		-	-	-	-	-
Nylon 9,9
Paraffin	8002-74-2		28.1	28.1	0.0		-	-	-	-	-		-	-	-	-	-
Paraffin			3.71(7)	3.71(7)	0.00(7)
Phenoxy resin	26402-79-9		-	-	-		-	-	-	-	-		-	-	-	-	-
Phenoxy resin
Poly 2-ethylhexyl acrylate	9003-77-4	30.1	28.9	1.3	-	-	-	-	-	-	-	-	-	-
Poly 2-ethylhexyl acrylate		0.90(3)	1.57(3)	0.78(3)
Poly 2-ethylhexyl methacrylate	25719-51-1	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly 2-ethylhexyl methacrylate
Poly iso-butyl methacrylate (PIBMA)	9011-15-8	30.9	26.3	4.7	-	-	-	-	-	20.0	18.3	4.9	6.3	9.4
Poly iso-butyl methacrylate (PIBMA)		0.00(2)	0.49(2)	0.49(2)						2.11(3)	0.93(3)	5.12(3)	2.10(3)
Poly n-butyl acrylate	9003-49-0	32.2	28.6	3.6	-	-	-	-	-	-	-	-	-
Poly n-butyl acrylate		2.12(2)	2.55(2)	0.42(2)
Poly n-butyl methacrylate (PnBMA)	95608-33-7	32.3	27.3	5.0	-	-	-	-	-	18.4	16.0	6.2	6.6	9.5
Poly n-butyl methacrylate (PnBMA)		1.56(5)	2.59(5)	1.78(5)							-(1)	-(1)	-(1)	-(1)
Poly t-butyl methacrylate (PtBMA)	25189-00-9	30.5	26.5	4.0	-	-	-	-	-	-	-	-	-	-
Poly t-butyl methacrylate (PtBMA)		0.00(2)	0.42(2)	0.42(2)
Poly(L-alanine)	25191-17-7	45.2	36.0	9.2	-	-	-	-	-	-	-	-	-	-
Poly(L-alanine)		-(1)	-(1)	-(1)
Polyacetylene (polyethyne)	-	51.5	48.2	3.4	-	-	-	-	-	-	-	-	-	-
Polyacetylene (polyethyne)		0.71(2)	1.77(2)	1.06(2)
Polyacrylamide	9003-05-8	52.3	26.5	25.8	-	-	-	-	-	-	-	-	-	-
Polyacrylamide		-(1)	-(1)	-(1)
Polyacrylonitrile (PAN)	25014-41-9	-	-	-	-	-	-	-	-	27.4	21.7	14.1	9.1	10.9
Polyacrylonitrile (PAN)											-(1)	-(1)	-(1)	-(1)
Polybenzyl methacrylate	25085-83-0	-	-	-	-	-	-	-	-	-	-	-	-	-
Polybenzyl methacrylate
Polybutadiene	9003-17-2	-	-	-	-	-	-	-	-	18.0	17.5	2.3	3.4	6.6
Polybutadiene											-(1)	-(1)	-(1)	-(1)
Polybutylene isophthalate	-	47.8	34.9	12.9	-	-	-	-	-	-	-	-	-	-
Polybutylene isophthalate		-(1)	-(1)	-(1)
Polybutylene terephthalate (PBT)	26062-94-2	46.0	42.0	4.1	47.1	45.8	1.3	0.8	0.6	-	-	-	-	-
Polybutylene terephthalate (PBT)		0.24(4)	2.83(4)	2.92(4)	-(1)	-(1)	-(1)	-(1)	-(1)
Polycarbonate (PC)	24936-68-3	43.4	38.2	5.2	-	-	-	-	-	22.2	19.6	8.8	5.7	10.2
Polycarbonate (PC)		8.21(3)	9.24(3)	3.69(3)							1.75(3)	2.58(3)	1.04(3)	4.06(3)
Polychloroprene	9010-98-4	43.6	38.8	4.8	-	-	-	-	-	-	-	-	-	-
Polychloroprene		0.00(2)	0.14(2)	0.14(2)
Polychlorotrifluoroethylene	9002-83-9	29.5	22.6	6.9	-	-	-	-	-	16.5	15.6	2.5	4.7	5.8
Polychlorotrifluoroethylene		1.78(3)	1.19(3)	2.89(3)							2.10(3)	1.46(3)	2.44(3)	1.56(3)
Polydiethylsiloxane (PDES)	63148-61-8	25.7	23.8	1.9	-	-	-	-	-	-	-	-	-	-
Polydiethylsiloxane (PDES)		-(1)	-(1)	-(1)
Poly(dimethylaminoethylmethacrylate)	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly(dimethylaminoethylmethacrylate)
Polydimethylsiloxane (PDMS)	9016-00-6	205	19.2	1.3	-	-	-	-	-	-	-	-	-	-
Polydimethylsiloxane (PDMS)		1.16(6)	1.48(6)	0.66(6)
Polyepichlorohydrin	24969-06-0	-	-	-	-	-	-	-	-	-	-	-	-	-
Polyepichlorohydrin
Polyetheretherketone (PEEK)	29658-26-2	42.1	36.2	5.9	-	-	-	-	-	-	-	-	-	-
Polyetheretherketone (PEEK)		-(1)	-(1)	-(1)
Polyetherimide (PEI)	61128-46-9	-	-	-	-	-	-	-	-	19.8	17.7	6.0	6.4	4.8
Polyetherimide (PEI)											1.07(5)	1.14(5)	2.43(5)	1.70(5)
Polyethersulfone (PES)	25154-01-2	47.0	40.0	7.0	-	-	-	-	-	21.0	18.3	8.2	6.4	6.3
Polyethersulfone (PES)		-(1)	-(1)	-(1)							0.91(6)	3.10(6)	2.33(6)	2.61(6)
Polyethyl acrylate (PEA)	9003-32-1	37.0	30.6	6.4	-	-	-	-	-	-	-	-	-	-
Polyethyl acrylate (PEA)		-(1)	-(1)	-(1)
Polyethyl methacrylate (PEMA)	9003-42-3	35.9	26.9	9.0	-	-	-	-	-	20.0	17.5	8.5	4.7	9.6
Polyethyl methacrylate (PEMA)		-(1)	-(1)	-(1)							1.34(3)	0.62(3)	3.82(3)	1.99(3)
Polyethylene oxide (PEO, PEG, polyethylene glycol)	25322-68-3	42.8	30.8	12.1	45.1	44.3	0.8	0.02	58.0	-	-	-	-	-
Polyethylene oxide (PEO, PEG, polyethylene glycol)		0.07(2)	0.21(2)	0.14(2)	1.59(4)	1.34(4)	1.60(4)	0.03(4)	10.2(4)
Polyethylene terephthalate (PET)	25038-59-9	43.7	36.6	7.2	45.3	42.6	1.8	0.3	3.7	20.8	18.7	6.3	6.7	6.5
Polyethylene terephthalate (PET)		3.42(16)	4.64(16)	3.42(16)	0.78(2)	2.83(2)	0.71(2)	0.21(2)	1.06(2)		1.25(8)	2.03(8)	2.80(8)	3.36(8)
Polyethylene (PE)	9002-88-4	34.2	32.8	1.4	31.7	31.5	0.2	0.1	0.9	17.6	16.8	3.8	3.8	6.6
Polyethylene (PE)		2.45(19)	2.89(19)	1.73(19)	2.86(10)	2.93(10)	0.27(10)	0.19(10)	1.39(10)		0.88(7)	1.94(7)	2.52(7)	2.84(7)
Poly(heptadecafluorooctyl methacrylate)	-	15.3	13.9	1.4	-	-	-	-	-	-	-	-	-	-
Poly(heptadecafluorooctyl methacrylate)		-(1)	-(1)	-(1)
Poly(heptafluoroisopropyl acrylate)	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly(heptafluoroisopropyl acrylate)
Poly(heptafluoroisopropyl methacrylate)	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly(heptafluoroisopropyl methacrylate)
Poly(hexachlorobutadiene)	-	41.5	40.7	0.8	-	-	-	-	-	-	-	-	-	-
Poly(hexachlorobutadiene)		-(1)	-(1)	-(1)
Poly(hexafluoropropylene)	-	14.9	13.6	1.3	-	-	-	-	-	-	-	-	-	-
Poly(hexafluoropropylene)		2.10(3)	1.48(3)	1.55(3)
Poly(hexyl methacrylate)	25087-17-6	30.0	27.6	2.5	-	-	-	-	-	-	-	-	-	-
Poly(hexyl methacrylate)		0.00(2)	0.78(2)	0.78(2)
Poly(2-hydroxyethyl methacrylate)	24249-16-5	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly(2-hydroxyethyl methacrylate)
Polyimide (PI)	25038-81-7	47.0	38.2	8.8	44.0	42.5	1.5	0.1	6.0	-	-	-	-	-
Polyimide (PI)		8.49(2)	16.8(2)	8.27(2)	-(1)	-(1)	-(1)	-(1)	-(1)
Polyisobutylene (PIB, butyl (rubber)	9003-27-4	33.6	33.6	0.0	25.0	25.0	0.0	0.0	0.0	17.1	16.4	1.7	4.7	7.9
Polyisobutylene (PIB, butyl (rubber)		-(1)	-(1)	-(1)	-(1)	-(1)	-(1)	-(1)	-(1)		1.26(6)	2.15(6)	2.08(6)	2.46(6)
Polyisoprene (PIP)	9003-31-0	-	-	-	-	-	-	-	-	18.4	18.1	2.4	2.3	10.3
Polyisoprene (PIP)											2.32(3)	1.40(3)	2.66(3)	3.40(3)
Polylauryl methacrylate	25719-52-2	-	-	-	-	-	-	-	-	-	-	-	-	-
Polylauryl methacrylate
Polymethacrylonitrile (PMAN)	25067-61-2	-	-	-	-	-	-	-	-	23.7	17.2	14.4	7.6	3.8
Polymethacrylonitrile (PMAN)											-(1)	-(1)	-(1)	-(1)
Polymethyl acrylate (PMA)	25087-26-7	41.4	35.6	5.8	-	-	-	-	-	-	-	-	-	-
Polymethyl acrylate (PMA)		0.85(4)	4.12(4)	4.45(4)
Polymethyl methacrylate (PMMA, acrylic, plexiglas)	9011-14-7	43.5	35.9	7.8	42.2	41.6	0.6	0.0	11.1	21.3	17.9	10.1	5.4	11.0
Polymethyl methacrylate (PMMA, acrylic, plexiglas)		2.88(14)	4.09(13)	3.79(13)	2.97(11)	2.36(11)	0.89(11)	0.04(11)	5.84(11)		1.37(5)	4.46(5)	3.73(5)	4.63(5)
Poly(4-methyl pentene-1)	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly(4-methyl pentene-1)
Poly a-methyl styrene	25014-31-7	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly a-methyl styrene
Polymethylphenylsiloxane	9005-12-3	-	-	-	-	-	-	-	-	-	-	-	-	-
Polymethylphenylsiloxane
Polymethylphenylsilylene	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Polymethylphenylsilylene
Poly(nonafluoroisobutyl acrylate)	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly(nonafluoroisobutyl acrylate)
Polyoctyl methacrylate	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Polyoctyl methacrylate
Polyoxymethylene (POM, polyacetal, polymethylene oxide)	24969-26-4	39.0	26.2	12.8	-	-	-	-	-	-	-	-	-	-
Polyoxymethylene (POM, polyacetal, polymethylene oxide)		7.99(2)	6.15(2)	1.84(2)
Polyphenyl methacrylate	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Polyphenyl methacrylate
Polyphenylene oxide (PPO)	25134-01-4	46.0	36.0	10.0	-	-	-	-	-	20.1	17.9	3.1	8.5	8.6
Polyphenylene oxide (PPO)		-(1)	-(1)	-(1)							-(1)	-(1)	-(1)	-(1)
Polyphenylene sulfide (PPS)	26125-40-6	46.8	44.0	2.8	-	-	-	-	-	19.8	18.7	5.3	3.7	6.7
Polyphenylene sulfide (PPS)		3.29(3)	3.50(3)	0.71(3)							-(1)	-(1)	-(1)	-(1)
Poly(phosphazene)	-	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly(phosphazene)
Poly n-propyl methacrylate	2210-79-9	-	-	-	-	-	-	-	-	-	-	-	-	-
Poly n-propyl methacrylate
Polypropylene glycol (PPG, polypropylene oxide)	25322-69-4	31.7	31.3	0.4	-	-	-	-	-	-	-	-	-	-
Polypropylene glycol (PPG, polypropylene oxide)		-(1)	-(1)	-(1)
Polypropylene isophthalate	-	49.3	35.1	14.2	-	-	-	-	-	-	-	-	-	-
Polypropylene isophthalate		-(1)	-(1)	-(1)
Polypropylene (PP)	^(a)	30.1	27.7	2.4	32.0	31.7	0.3	0.2	0.4	18.0	17.7	2.9	1.2	6.2
Polypropylene (PP)		2.42(11)	2.46(11)	2.45(11)	3.99(8)	3.56(8)	0.76(8)	0.45(8)	0.76(8)		0.46(2)	2.80(2)	1.71(2)	1.76(2)
Polystearyl methacrylate	25639-21-8	-	-	-	-	-	-	-	-	-	-	-	-	-
Polystearyl methacrylate
Polystyrene (PS)	9003-53-6	41.7	37.0	5.0	36.9	37.9	-0.9	0.1	2.2	23.9	22.8	5.8	4.3	12.7
Polystyrene (PS)		1.24(8)	3.47(9)	2.84(8)	5.80(3)	4.32(3)	1.68(3)	0.20(3)	2.72(3)		-(1)	-(1)	-(1)	-(1)
Polysulfone (PSU)	25135-51-7	46.6	30.4	16.2	-	-	-	-	-	21.5	18.5	8.5	7.0	9.4
Polysulfone (PSU)		-(1)	-(1)	-(1)							2.17(3)	2.61(3)	1.12(3)	1.69(3)
Polytetrafluoroethylene (PTFE)	9002-84-0	22.2	21.3	0.9	20.8	19.9	0.9	0.1	1.6	16.7	16.2	1.8	3.4	3.9
Polytetrafluoroethylene (PTFE)		2.54(9)	2.71(10)	0.96(9)	0.99(2)	0.35(2)	1.34(2)	0.20(2)	2.26(2)		-(1)	-(1)	-(1)	-(1)
Polytetrahydrofuran (PTHF)	25190-06-1	31.9	27.2	4.7	-	-	-	-	-	-	-	-	-	-
Polytetrahydrofuran (PTHF)		0.00(2)	0.28(2)	0.28(2)
Polytetramethylene oxide	-	31.9	27.4	4.5	-	-	-	-	-	-	-	-	-	-
Polytetramethylene oxide		-(1)	-(1)	-(1)
Polytrifluoroethylene	24980-67-4	27.5	22.0	5.4	25.4	23.1	2.3	1.8	0.7	-	-	-	-	-
Polytrifluoroethylene		3.65(3)	2.10(3)	3.20(3)	-(1)	-(1)	-(1)	-(1)	-(1)
Polyurethanes	-	39.3	30.8	8.6	30.0	30.9	-0.9	0.02	10.0	22.8	18.8	10.0	8.2	9.8
Polyurethanes		2.60(8)	3.63(8)	3.95(8)	-(1)	-(1)	-(1)	-(1)	-(1)		1.53(11)	2.54(11)	3.09(11)	3.48(11)
Polyvinyl acetate (PVA)	9003-20-7	37.7	24.8	13.0	44.5	42.6	1.9	0.04	22.3	25.7	20.9	11.3	9.7	13.7
Polyvinyl acetate (PVA)		2.89(5)	1.65(5)	1.53(5)	-(1)	-(1)	-(1)	-(1)	-(1)		-(1)	-(1)	-(1)	-(1)
Polyvinyl alcohol (PVOH)	25213-24-5	-	-	-	42.0	42.0	0.0	0.0	37.0	25.2	14.7	14.1	14.9	10.5
Polyvinyl alcohol (PVOH)					-(1)	-(1)	-(1)	-(1)	-(1)		2.51(4)	2.13(4)	2.18(4)	1.38(4)
Polyvinyl butyral	63148-65-2	-	-	-	-	-	-	-	-	24.6	19.1	9.5	12.2	10.0
Polyvinyl butyral											0.92(3)	4.50(3)	1.65(3)	1.53(3)
Polyvinyl butyrate	-	31.1	25.8	5.3	-	-	-	-	-	-	-	-	-	-
Polyvinyl butyrate		-(1)	-(1)	-(1)
Polyvinyl chloride (PVC)	9002-86-2	40.1	37.4	2.8	39.8	38.7	1.0	0.1	3.1	20.0	16.8	8.9	6.1	8.5
Polyvinyl chloride (PVC)		3.80(9)	3.93(10)	2.36(9)	4.76(6)	4.33(6)	0.96(6)	0.15(6)	2.31(6)		1.65(5)	1.95(5)	1.78(5)	3.94(5)
Polyvinyl decanoate	-	28.9	27.1	1.8	-	-	-	-	-	-	-	-	-	-
Polyvinyl decanoate		-(1)	-(1)	-(1)
Polyvinyl dodecanoate	-	29.1	27.8	1.3	-	-	-	-	-	-	-	-	-	-
Polyvinyl dodecanoate		-(1)	-(1)	-(1)
Polyvinyl ethyl ether (polyethoxyethylene)	25104-37-4	-	-	-	-	-	-	-	-	-	-	-	-	-
Polyvinyl ethyl ether (polyethoxyethylene)
Polyvinyl fluoride (PVF)	24981-14-4	38.6	34.0	4.6	37.5	35.6	1.9	2.8	6.0	-	-	-	-	-
Polyvinyl fluoride (PVF)		2.85(5)	5.72(5)	4.38(5)	1.30(3)	2.08(3)	0.85(3)	4.73(3)	6.62(3)
Polyvinyl formal	63450-15-7	-	-	-	-	-	-	-	-	-	-	-	-	-
Polyvinyl formal
Polyvinyl hexadecanoate	-	30.9	29.8	1.1	-	-	-	-	-	-	-	-	-	-
Polyvinyl hexadecanoate		-(1)	-(1)	-(1)
Polyvinyl hexanoate	-	28.9	25.1	3.8	-	-	-	-	-	-	-	-	-	-
Polyvinyl hexanoate		-(1)	-(1)	-(1)
Polyvinyl octanoate	-	28.7	26.5	2.2	-	-	-	-	-	-	-	-	-	-
Polyvinyl octanoate		-(1)	-(1)	-(1)
Polyvinyl proprionate	25035-84-1	34.0	26.5	7.5	-	-	-	-	-	-	-	-	-	-
Polyvinyl proprionate		-(1)	-(1)	-(1)
Polyvinyl pyrrolidone (PVP)	9003-39-8	-	-	-	46.0	43.4	2.6	0.2	22.5	-	-	-	-	-
Polyvinyl pyrrolidone (PVP)					3.61(2)	0.00(2)	3.61(2)	0.28(2)	10.2(2)
Polyvinylidene chloride (PVDC, Saran)	9002-85-1	45.3	40.4	4.9	40.3	40.4	-0.1	0.0	2.6	23.1	19.0	9.6	9.0	5.8
Polyvinylidene chloride (PVDC, Saran)		0.38(4)	2.93(4)	2.91(4)	-(1)	-(1)	-(1)	-(1)	-(1)		1.98(2)	0.64(2)	1.70(2)	2.62(2)
Polyvinylidene fluoride (PVDF)	24937-79-9	34.4	25.7	8.7	30.5	28.6	1.9	10.5	0.08	23.2	17.0	12.1	10.2	4.1
Polyvinylidene fluoride (PVDF)		4.17(4)	4.64(4)	4.81(4)	-(1)	-(1)	-(1)	-(1)	-(1)		-(1)	-(1)	-(1)	-(1)
Polyxylylene (parylene)	-	46.3	45.7	0.6	-	-	-	-	-	-	-	-	-	-
Polyxylylene (parylene)		-(1)	-(1)	-(1)
Thermoplastic polyolefin (TPO)	-	30.9	28.5	2.3	-	-	-	-	-	-	-	-	-	-
Thermoplastic polyolefin (TPO)		3.45(11)	2.80(11)	3.63(11)

(a) Atactic PP CAS #9003-08-0; isotactic PP CAS #25085-53-4

(b) Aluminum foil, while obviously not a polymer, is included due to its widespread use in package converting and other industries.

⁽¹⁾ Names which are most widely used to describe the material or family of materials (e.g., polyurethanes and epoxies) at hand are preferred here. Commonly used acronyms and synonyms are also shown.

⁽²⁾ CAS (Chemical Abstract Series) numbers are shown where available. In a number of instances, more than one CAS number is assigned to a given polymer — in some cases the details and nuances of these divergences are not at all clear. We have tried to reference the CAS number which appears to have the widest use with reference to the solid state properties of the given polymer.

⁽³⁾ γ_s: Total surface free energy in mJ/m² (equivalent to dynes/cm), as reported in polar/dispersion analyses.

⁽⁴⁾ γ_s^d: Dispersion component of surface free energy in mJ/m² (equivalent to dynes/cm), as reported in polar/dispersion analyses.

⁽⁵⁾ γ_s^p: Polar component of surface free energy in mJ/m² (equivalent to dynes/cm), as reported in polar/dispersion analyses.

⁽⁶⁾ γ_s: Total surface free energy in mJ/m² (equivalent to dynes/cm), as reported in acid—base analyses.

⁽⁷⁾ γ_s^LW: Lipschitz—van der Waals (non-polar) component of surface free energy in mJ/m² (equivalent to dynes/cm), as reported in acid—base analyses.

⁽⁸⁾ γ_s^AB: Lewis acid—base interaction component of surface free energy in mJ/m² (equivalent to dynes/cm), as reported in acid—base analyses.

⁽⁹⁾ γ_s^-: Base polarity (electron-donor) component of surface free energy in mJ/m² (equivalent to dynes/cm), as reported in acid—base analyses.

⁽¹⁰⁾ γ_s⁺: Acid polarity (electron-acceptor) component of surface free energy in mJ/m² (equivalent to dynes/cm), as reported in acid—base analyses.

⁽¹¹⁾ δ: Total Hansen solubility parameter (square root of the sum of squares of the average values for dispersion, polar, and hydrogen bonding components), in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹²⁾ δ_D: Hansen dispersion solubility parameter, in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹³⁾ δ_P: Hansen polar solubility parameter, in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹⁴⁾ δ_H: Hansen hydrogen bonding solubility parameter, in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹⁵⁾ R_o: Interaction radius. All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.