PRODUCT AND COMPANY IDENTIFCATION
Product identifiers
Product name: ACCU DYNE TESTTM Marker Pens
Recommended use of product: Surface energy (wettability) measurement of non-absorptive solids
Supplier: Diversified Enterprises
101 Mulberry St., Ste 2N
Claremont, NH 03743 USA
603-543-0038
Emergency telephone number: Chemtrec 1-800-424-9300
HAZARDS IDENTIFCATION
Classification:
2-ethoxyethanol and Methyl Violet 28 are considered hazardous by the 2012 OSHA Standard (29 CFR 1910.1200).
Acute toxicity - oral: 2-ethoxyethanol, Category 4; Methyl Violet 28, Category 4
Acute toxicity - ingestion: 2-ethoxyethanol, Category 4
Acute toxicity - inhalation: 2-ethoxyethanol, Category 4
Serious eye damage/irritation: 2-ethoxyethanol, Category 28; Methyl Violet 28, Category 2A·
Reproductive toxicity: 2-ethoxyethanol, Category 18; formamide, Category 18
Specific organ toxicity, repeated exposure: 2-ethoxyethanol, Category 2; formamide, Category 2 Flammable liquids: 2-ethoxyethanol, Category 3
Label elements:
Pictograms: Health Hazard, Exclamation Mark, Flammable
Signal word: Danger
Hazard statements:
H222: Flammable liquid and vapor H302: Harmful if swallowed
H313: Causes eye irritation H332: Harmful if inhaled
H351: Suspected of causing cancer
H360: May damage fertility of the unborn child
H373: May cause damage to organs through prolonged or repeated exposure if swallowed
Precautionary statements • Prevention:
P201: Obtain special instructions before use
P202: Do not handle until all safety precautions have been read and understood P210: Keep away from heat, sparks, or open flames
P233: Keep container tightly closed
P264: Wash hands and face thoroughly after handling
P270: Do not eat, drink or smoke when using this product
P271: Use only in a well-ventilated area
P280: Wear long-sleeved clothing and gloves
...
If in eyes: Rise with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists get medical attention.
If on skin: Remove all contaminated clothing immediately. Rinse skin with water. If skin irritation occurs, get medical attention.
If swallowed: Call a poison center or physician if you feel unwell.
P501: Dispose of contents/container to an approved waste disposal plant
COMPOSITION/INFORMATION ON INGREDIENTS
| Constituent | CAS No. | Concentration |
|---|---|---|
| 2-ethoxyethanol, Reagent Grade (C)* | 110-80-5 | See below |
| Formamide, ACS Reagent Grade (F)** | 75-12-7 | See below |
| Water, Reagent Grade (H) | 7732-18-5 | See below |
| Methyl Violet 2B | 8004-87-3 | 3.0 grams/liter (0.3% w/v) |
* 2-ethoxyethanol is also known as ethylene glycol monoethyl ether, cellosolve solvent, ethyl cellosolve, and glycol ether EE
** Formamide is also known as methanamide.
| Volumetric Mix Percentages by Dyne Level | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Level | C | F | Level | C | F | Level | F | H | ||
| 30 | 100.0% | 0.0% | 44 | 22.0% | 78.0% | 57 | 100.0% | 0.0% | ||
| 31 | 97.5% | 2.5% | 45 | 19.7% | 80.3% | 58 | 81.2% | 18.8% | ||
| 32 | 89.5% | 10.5% | 46 | 17.2% | 82.8% | 59 | 73.1% | 26.9% | ||
| 33 | 81.0% | 19.0% | 47 | 15.0% | 85.0% | 60 | 65.0% | 35.0% | ||
| 34 | 73.5% | 26.5% | 48 | 13.0% | 87.0% | 61 | 56.0% | 44.0% | ||
| 35 | 65.0% | 35.0% | 49 | 11.1% | 88.9% | 62 | 47.0% | 53.0% | ||
| 36 | 57.5% | 42.5% | 50 | 9.3% | 90.7% | 63 | 38.8% | 61.2% | ||
| 37 | 51.5% | 48.5% | 51 | 7.8% | 92.2% | 64 | 30.6% | 69.4% | ||
| 38 | 46.0% | 54.0% | 52 | 6.3% | 93.7% | 65 | 24.4% | 75.6% | ||
| 39 | 41.0% | 59.0% | 53 | 4.9% | 95.1% | 66 | 18.2% | 81.8% | ||
| 40 | 36.5% | 63.5% | 54 | 3.5% | 96.5% | 67 | 13.4% | 86.6% | ||
| 41 | 32.5% | 67.5% | 55 | 2.2% | 97.8% | 68 | 8.6% | 91.4% | ||
| 42 | 28.5% | 71.5% | 56 | 1.0% | 99.0% | 69 | 6.1% | 93.9% | ||
| 43 | 25.3% | 74.7% | 70 | 3.6% | 96.4% | |||||
| 72 | 0.0% | 100.0% | ||||||||
FIRE FIGHTING MEASURES
Suitable extinguishing media: Carbon dioxide, alcohol-resistant foam, dry chemical, or water spray.
Unsuitable extinguishing media: No data available.
Special hazards arising from the substance: 2-ethoxyethanol is flammable. It may be ignited by heat, sparks, or flames. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas.
Advice for firefighters: Wear self-contained brathing apparatus for firefighting if necessary.
ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protective equipment. Ensure adequate ventilation. Avoid breating vapors.
Environmental precautions: Prevent futher leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for cleaning up: Soak up with inert absorptive material and put into a suitable chemical waste disposal container.
HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with skin and eyes. Avoid inhalation of vapor.
Conditions for safe storage: Keep botles securely closed in a dry, well-ventilated place when not in use. Avoid strong oxidizing agents.
EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters:
2-ethoxyethanol:
OSHA Table Z-1 - 200 ppm TWA
ACGIH TLV - 5 ppm TWA
Formamide:
OSHA Table Z-1 - 20 ppm TWA
ACGIH TLV - 10 ppm TWA
Appropriate engineering controls: Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice.
Personal protective equipment:
Eye protection: Safety glasses.
Skin protection: Long-sleeved clothing. Gloves.
Hygiene measures: Avoid contact with skin, eyes, and clothing. Wash hands before breaks and immediately after handling product. Do not eat, drink, or smoke while using these test fluids.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance and form: Blue-violet liquid
Odor: Mild, slightly sweet to ammoniacal
Odor threshold: No data available.
pH: No data available.
Evaporation rate: No data available.
Other properties:
| Property | 2-ethoxyethanol | Formamide | Water | Methyl Violet 28 |
|---|---|---|---|---|
| Freezing/melting point | -90C | 2C |
|
137C |
| Boiling point | 135C | 210C | 100C | nodata |
| Flash point, closed cup | 43C | 150C | n/a | n/a |
| Autoignition temperature | 235C | nodata | n/a | n/a |
| Flammability/explosion limits | 1.8-14.0% | 2.7-19.0% | n/a | n/a |
| Vapor pressure @ 20C | 5.05 hPa | 0.11 hPa | 3.11 hPa | n/a |
| Vapor density (air = 1.0) | 3.11 | 1.56 | nodata | n/a |
| Specific density @ 20C | 0.929 | 1.134 | 0.998 | n/a |
| Solubility in water | miscible | miscible | n/a | miscible |
| Partition coefficient | -0.32 | no data | n/a | n/a |
| Decomposition temperature | no data | >180C | n/a | no data |
| Molecular weight | 90.12 | 45.04 | 18.01 | 393.96 |
The most likely route of entry is by dermal absorption. Routes of entry include eye and skin contact, ingestion, and inhalation. Specific health effects are broken out by the two primary ingredients.
LD50 oral rat = 1746 mg/kg (EU Commission dataset)
LD50 oral mouse = 2451 mg/kg (RTECS)
LD50 dermal rabbit = 3300 mg/kg (LOLI, EU Commission dataset and RTECS)
LC50 inhalation rat = 4267 ppm 4 h; 15 mg/I 4 h
LC50 inhalation mouse = 1820 ppm 7 h
Carcinogenic effects: Not considered carcinogenic. Not listed by ACGIH, IARC, NTP, or OSHA HCS.
Mutagenc effects: May affect genetic material based on animal test data.
Reproductive effects: May cause adverse reproductive effects. May impair fertility.
Teratogenic effects: May cause birth defects.
Specific target organ toxicity, single exposure: No information available.
Specific target organ toxicity, repeated exposure: May cause damage to central nervous system, blood, kidneys, liver, bone marrow.
Aspiration hazard: No data available.
LD50 oral rat = 5.325 mg/kg (OECD Test Guideline 401)
LC50 inhalation rat = 21 mgA 4 h (OECD Test Guideline 403)
LD50 dermal rat = >3,000 mg/kg
Carcinogenic effects: Not identified as probable, possible, or confirmed human carcinogen by IARC, ACGIH, NTP, or OSHA.
Mutagenic effects: Mouse, male and female by micronucleus test - negative.
Reproductive effects: Presumed human reproductive toxicant.
Teratogenic effects: May cause birth defects.
Specific target organ toxicity, single exposure: No information available.
Specific target organ toxicity, repeated exposure: Oral - may cause damage to blood or organs through prolonged or repeated exposure.
Aspiration hazard: No data available.
Freshwater algae: 1,000 mg/I EC50 Desmodesmus subspicatus 72 h.
Freshwater fish: 10,000 mgA LC50 Lepomis macrochirus 96 h static 1.
Water flea: 10,000 mg/I EC50 Daphnia magna 48 h.
Persistence and degradability: No data available.
Bioaccumulative potential: Potential for bioconcentration in aquatic organisms is low.
Mobility: Expected to have high mobility in soil.
Freshwater algae: >500 mgA EC50 Desmodesmus subspicatus 72 h.
Freshwater fish: 6,569 mg/I LC50 Leuciscus idus 96 h.
Water flea: >500 mgA EC50 Daphnia magna 72 h.
Persistence and degradability: Aerobic - exposure time 28 d; 99% readily biodegradable (OECD Test Guideline 301A).
Bioaccumulative potential: No data available.
Mobility: No data available.
Waste must be disposed of in accordance with federal, state, and local environmental control regulations.
Spent material samples must be handled with care. Disposal of these contaminated materials also presents exposure hazards, and should not be handled without gloves or in areas with poor ventilation.
UN No.: UN 1171
Proper shipping name: Ethylene glycol monoethyl ether
Hazard class: 3
Packing group: III
ERG No.: 127
Symbol: R4
UN No.: UN 1171
Proper shipping name: Ethylene glycol monoethyl ether
Hazard class: 3
Packing group: III
UN No.: UN 1171
Proper shipping name: Ethylene glycol monoethyl ether
Hazard class: 3
Packing group: III
EMS: F-E
UN No.: UN 1171
Proper shipping name: Ethylene glycol monoethyl ether
Hazard class: 3
Packing group: III
ERG Code: 3L
SARA Title Ill, Section 302 Components: None
SARA 313 Components: 2-ethoxyethanol
SARA 311/312 Hazards Acute health hazard, chronic health hazard, fire hazard
U.S. TSCA: 2-ethoxyethanol present, Section 5(a)2: 40 CFR 721.10001
Canada DSL:2-ethoxyethanol present
Korea KECL: 2-ethoxyethanol present KE-13667
Philippines (PICCS): 2-ethoxyethanol present
Japan ENCS: 2-ethoxyethanol present (7)-97 (2)-411 (2)-2424
China: 2-ethoxyethanol present
Australia (AICS): 2-ethoxyethanol present
EINECS No.:2-ethoxyethanol present 203-804-1
California Directors List of Hazardous Substances: 2-ethoxyethanol resent
California Proposition 65: 2-ethoxyethanol is known to the State of California to cause birth defects or other reproductive harm.
Massachusetts RTK: 2-ethoxyethanol, formamide present
Minnesota: 2-ethoxyethanol present
New Jersey RTK and (EHS) List 2-ethoxyethanol, formamide present
Pennsylvania RTK: 2-ethoxyethanol, formamide present
Rhode Island RTK: 2-ethoxyethanol present
CERCLA/SARA: Reportable quantity, 2-ethoxyethanol = 1,000 lb.
Copyright 2015 Diversified Enterprises. Valid as of December 21, 2024.
License is granted to make unlimited paper copies for internal use only.
The above information is believed to be correct, but does not claim to be all-inclusive and is to be used only as a guide. This information should not be taken as a warranty for which Diversified Enterprises assumes legal responsibility. It is provided solely for consideration, investigation, and verification. The information contained in this document is based on our current understanding of available data and is applicable to the product with regard to appropriate safety precautions. It is the user's responsibility to develop proper methods based on the actual conditions of use.